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Yes Vulture is out
Marvel Universe Infinite Series 2015 Vulture Loose Action Figure | eBay
It depends on which SINISTER SIX you want...
Original Sinister Six[edit]
After suffering three defeats in a row from Spider-Man, Doctor Octopus contacts every known supervillain that had crossed paths with Spider-Man. Only Vulture, Electro, Kraven the Hunter, Mysterio, and Sandman respond. As none of the members are willing to relinquish the honor of killing Spider-Man themselves, they decide to challenge Spider-Man individually, with the order in which they face him determined by random drawing. The Sinister Six kidnap Daily Bugle secretary Betty Brant and Aunt May, holding them hostage in order to force Spider-Man to confront them. Spider-Man defeats the Sinister Six one-by-one, mocking their decision to battle him individually instead of as a team.[2]